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Tailoring aggregation-induced emission in luminescent solar concentrators through controlled polymerization
2025 / Communications ChemistryLuminescent solar concentrators (LSCs) hold great potential as versatile energy conversion systems for diverse applications. Here, we explore the covalent incorporation of aggregation-induced emission (AIE) luminogens into polymeric backbones for LSCs. Copolymers based on methyl-methacrylate and an AIE-active monomer (tetraphenyl ethylene methacrylate - TPEMA) are ...
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Polyferrocene-Based Cubosomes: Conversion to Magnetic Mesoporous Microparticles, Supramolecular Modification, and Oxidation Response
2025 / Advanced Functional MaterialsPolymer cubosomes(PCs)areanemergingclassofmesoporousmicroparticles that are produced through solution self-assembly of highly asymmetric block copolymers (BCPs). They proved useful for encapsulation or templating replicas for catalysis and energy storage. Although PCs made from BCPs with intrinsic functions such as response to stimuli, degradation, or coordination ...
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2Dmaterials, infrared optical synapse, interlayer coupling, orientation de tection, van der Waals heterostructure
2025 / Advanced Photonics ResearchThe all-inorganic lead halide perovskites, including cesium lead iodide (CsPbI3), have attracted significant attention due to their possible applications in photo voltaics, light-emitting devices, and other optoelectronic technologies, driven by their intrinsic optoelectronic properties. This study introduces a simple, green, and scalable solution synthesis method ...
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Temperature dependency of energy shift of excitonic states in a donor–acceptor type TADF molecule
2025 / Nature CommunicationsIn recent years, thermally activated delayed fluorescence (TADF) has attracted intense attention owing to its straightforward application to high-efficiency organic light-emitting diodes. Further, to develop high-performance TADF materials, many researchers have designed novel molecules that have a small energy gap between the lowest excited singlet and triple...
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Investigating the effects of microwave plasma on bacterial cell structures, viability, and membrane integrity
2025 / Scientific ReportsPlasma-mediated bacterial inactivation holds great promise but presents several challenges. This study investigates the antibacterial effect of 2.45 GHz non-thermal microwave (MW) plasma on Staphylococcus aureus (S. aureus) and Salmonella abony (S. abony) suspended in phosphate-buffered saline (PBS). A 6-log reduction in both bacterial strains was achieved within...
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Ecofriendly first-derivative synchronous fluorometric method for simultaneous determination of atorvastatin and aspirin in pharmaceutical preparations
2025 / Scientific ReportsThe combination of atorvastatin (ATO) and aspirin (ASP) is widely prescribed for preventing cardiovascular diseases, particularly in individuals at risk of atherosclerosis and myocardial infarction. This study aims to develop and validate an eco-friendly spectrofluorimetric method using the first-derivative synchronous fluorescence (FDSSF) technique (Δ&lamb...
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Structural basis for the human SENP5’s SUMO isoform discrimination
2025 / Nature CommunicationsPost-translational SUMO modification is a widespread mechanism for regulating protein function within cells. In humans, SUMO-conjugated proteins are partially regulated by the deconjugating activity of six SENP family members. The proteolytic activity of these enzymes resides within a conserved catalytic domain that exhibits specificity for the two primary SUMO i...
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Albumin Corona Overturns Long-Acting Behaviors of Myristic Acid-Conjugated Quetiapine Nanosuspension
2025 / Advanced Healthcare MaterialsThis work aimed to investigate the interaction of a self-assembled myristic acid-conjugated quetiapine nanosuspension (QMN) with human serum albumin and its overturning effect on QMN’s long-acting performance. Albumin corona formation modified the physicochemical properties and pharmacokinetic profile of QMN by overturning its pH-responsiveness and nano-aggre...
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Single-molecule visualization of ATP-induced dynamics of the subunit composition of an ECF transporter complex under turnover conditions
2025 / Nature CommunicationsEnergy-Coupling Factor (ECF) transporters are ATP-binding cassette (ABC) transporters essential for uptake of vitamins and cofactors in prokaryotes. They have been linked to pathogen virulence and are potential targets for antimicrobials. ECF transporters have been proposed to use a unique transport mechanism where a substrate-translocating subunit (S-component) ...
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Pyrrole dicarboxylate substituted porphyrazine, microwave assisted synthesis and properties
2025 / Scientific ReportsIn this study, a new magnesium(II) porphyrazine derivative tetrasubstituted with dicarboxypyrrolyl moieties was synthesized. Two different approaches were used, utilizing conventional heating and microwave irradiation. The developed three-step processes were compared showing the superior performance of the microwave-assisted organic synthesis. The new macrocycle ...
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Geometric Adjustment of T Cell - Sensitive Nanorobots for Enhanced Stability
2025 / Advanced Healthcare MaterialsPersonalizeddendriticcell(DC)basedvaccinesofferpromising immunotherapeuticapproachesforcancersandinfectiousdiseasesby leveraginglivingDCstostimulateapatient’simmunesystemthrough interactionswithTcells.However,conventionalDC-basedvaccinesface significantchallenges, includinglimitedstabilityandshortstoragelifespanof thelivingcells.Toovercometheselimitations,sma...
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Solvent polarity effect on photophysical properties of some aromatic azo dyes with focus on tautomeric and toxicity competition
2025 / Scientific ReportsEdible dyes have become an essential part of modern life, widely appreciated for their safety and effectiveness in food coloring. Given the fundamental role of hydrogen bonding in chemical and biological systems, this study explores the photophysical properties of three commonly used aromatic azo food dyes–Ponceau 4R, Sunset Yellow, and Tartrazine–acr...
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Deciphering the effects of bixin on pulmonary alveolar adenocarcinoma migration and proliferation via targeting BAX/BCL-2 and Cyclin D1
2025 / Scientific ReportsThere is a tremendous upsurge in lung cancer incidences due to changing lifestyles and other environmental risk factors. Unfortunately, the use of clinical therapeutics is causing serious side effects and drug-resistant tumors. Taking account of the severity of lung cancer malignancy and the pressing need for natural therapeutics, we investigated the anticancer p...
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Photoactuating artificial muscle from supramolecular assembly of an overcrowded alkene-derived molecular switch
2025 / Nature CommunicationsThe amplification of molecular motion along length scales for macroscopic muscle-like functions, based on supramolecular polymers, provides attractive opportunities ranging from soft actuators to responsive biomedical materials. Taking the challenge to reveal dynamic assembly parameters governing muscle functions, we present the design of a photoswitch amphiphile...
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Exploring the Effect of Polymer Addition to the Room Temperature Synthesis of Colloidal Lead Halide Perovskite for Better Stability, Higher Passivation, and More Uniform Particle Size
2025 / Advanced Engineering MaterialsIn recent years, metal halide perovskites have emerged as a promising alternative to existing semiconductor materials in many applications due to its appealing properties. Despite perovskite huge potentials in many applications, they are still suffering from different kinds of stability issues that are hindering their market ability. Several attempts to stabilize p...
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